As always, you shouldn’t be digging through any files to change any CSS or images. You should be writing your custom CSS that overrides from your Child theme. You should be using some kind of inspector to locate the proper styles to edit and you can find PSD source images for the menu buttons in your download package.
For CSS changes, it’s a good idea to use a tool like firebug or Google Chrome’s built-in developer tools to locate them and then put the edits either in your child theme or in the “Custom CSS” option on your theme options page.
Also, here’s a helpful tutorial on how to use Firebug – http://vimeo.com/20917974. The only thing I’d suggest not doing is actually making edits to the theme’s CSS files, as it shows at the end of that video. However, the video serves as a good introduction to Firebug and how it can be used to find what CSS is effecting certain areas of your site without ever digging around in any files.